首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   50992篇
  免费   8673篇
  国内免费   5616篇
化学   36097篇
晶体学   629篇
力学   2997篇
综合类   336篇
数学   6038篇
物理学   19184篇
  2024年   47篇
  2023年   1081篇
  2022年   1257篇
  2021年   1800篇
  2020年   2254篇
  2019年   2121篇
  2018年   1779篇
  2017年   1727篇
  2016年   2539篇
  2015年   2532篇
  2014年   3017篇
  2013年   3842篇
  2012年   4790篇
  2011年   4822篇
  2010年   3354篇
  2009年   3131篇
  2008年   3363篇
  2007年   2968篇
  2006年   2679篇
  2005年   2286篇
  2004年   1750篇
  2003年   1384篇
  2002年   1190篇
  2001年   975篇
  2000年   845篇
  1999年   1011篇
  1998年   833篇
  1997年   777篇
  1996年   756篇
  1995年   719篇
  1994年   611篇
  1993年   518篇
  1992年   428篇
  1991年   389篇
  1990年   327篇
  1989年   239篇
  1988年   177篇
  1987年   163篇
  1986年   159篇
  1985年   139篇
  1984年   86篇
  1983年   93篇
  1982年   53篇
  1981年   39篇
  1980年   29篇
  1979年   18篇
  1977年   18篇
  1976年   20篇
  1975年   21篇
  1972年   19篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
61.
International Journal of Theoretical Physics - Designated verifier signatures are very useful in the applications such as e-voting and auction. In this paper, an identity-based quantum designated...  相似文献   
62.
The single-photon excitation and transmission spectra of strong-coupling hybrid optomechanics are theoretically analyzed, where a two-level system (TLS) is coupled to a mechanical resonator (MR), generating Jaynes–Cummings-type polariton doublets. In this model, both the optomechanical coupling and the TLS-MR coupling are strong. In this parameter region, polaron-assisted excitation reemission processes can strongly affect the single-photon excitation and output spectra of the cavity. It is found that the fine structure around each sideband can be used to characterize the TLS-MR and the effective TLS-photon couplings, even at the single-quantum level. Thus, the spectrum structures may make it possible to sensitively probe the quantum nature of a macroscopic mechanical element. A possible approach for tomographic reconstruction of the state of a TLS, utilizing the single-photon transmission spectra, is further provided.  相似文献   
63.
ABSTRACT

The complexes of H2X (X?=?O, S, Se) with hypervalent halogens YF3 and YF5 (Y?=?Cl, Br, I) have been studied. The σ-hole on the Y atom participates in a halogen bond with the lone pair on the chalcogen atom. In addition, some secondary interactions coexist with the halogen bond in most complexes. The interaction energy correlates with the nature of both X and Y atoms. In most cases, the complex is more stable for the heavier Y atom and the lighter X atom. Of course, there are some exceptions in H2X···YF3. YF3 forms a more stable complex with H2X than does YF5. These complexes are dominated by electrostatic interaction and the halogen bond involving H2S and H2Se exhibits some covalent character.

Halogen bond plays an important role in chemical reactions and multivalent halogens can regulate chemical reactions by participating in a halogen bond. Thus we compare the effect of the chalcogen electron donor on the strength and nature of halogen bonding involving multivalent halogens.  相似文献   
64.
We have developed a simple protocol for the preparation of 1,2-fluorohydrin by asymmetric hydrogenation of fluorinated allylic alcohols using an efficient azabicyclo thiazole-phosphine iridium complex. The iridium-catalyzed asymmetric synthesis of chiral 1,2-fluorohydrin molecules was carried out at ambient temperature with operational simplicity, and scalability. This method was compatible with various aromatic, aliphatic, and heterocyclic fluorinated compounds as well as a variety of polyfluorinated compounds, providing the corresponding products in excellent yields and enantioselectivities.

We have developed a simple protocol for the preparation of 1,2-fluorohydrin by asymmetric hydrogenation of fluorinated allylic alcohols using an efficient azabicyclo thiazole-phosphine iridium complex.  相似文献   
65.
Let x=(x',x')with x'∈Rk and x'∈R^N-k andΩbe a x'-symmetric and bounded domain in R^N(N≥2).We show that if 0≤a≤k-2,then there exists a positive constant C>0 such that for all x'-symmetric function u∈C0^∞(Ω)with∫Ω|■u(x)|^N-a|x'|^-adx≤1,the following uniform inequality holds1/∫Ω|x|^-adx∫Ωe^βa|u|N-a/N-a-1|x'|^-adx≤C,whereβa=(N-a)(2πN/2Γ(k-a/2)Γ(k/2)/Γ(k/2)r(N-a/2))1/N-a-1.Furthermore,βa can not be replaced by any greater number.As the application,we obtain some weighted Trudinger–Moser inequalities for x-symmetric function on Grushin space.  相似文献   
66.
Journal of Solid State Electrochemistry - In this work, we synthesized metal-organic framework Cu3(BTC)2 which was applied as the doping materials of anode electrodes in capacitive deionization...  相似文献   
67.
Improved charge extraction and wide spectral absorption promote power conversion efficiency of perovskite solar cells (PSCs). The state‐of‐the‐art carbon‐based CsPbBr3 PSCs have an inferior power output capacity because of the large optical band gap of the perovskite film and the high energy barrier at perovskite/carbon interface. Herein, we use alkyl‐chain regulated quantum dots as hole‐conductors to reduce charge recombination. By precisely controlling alkyl‐chain length of ligands, a balance between the surface dipole induced charge coulomb repulsive force and quantum tunneling distance is achieved to maximize charge extraction. A fluorescent carbon electrode is used as a cathode to harvest the unabsorbed incident light and to emit fluorescent light at 516 nm for re‐absorption by the perovskite film. The optimized PSC free of encapsulation achieves a maximum power conversion efficiency up to 10.85 % with nearly unchanged photovoltaic performances under 80 %RH, 80 °C, or light irradiation in air.  相似文献   
68.
Yang  Fan  Zhang  Yan  Li  Xiao-Xiao 《Numerical Algorithms》2020,83(4):1509-1530
Numerical Algorithms - This paper considers the inverse problem for identifying the initial value problem of a space-time fractional diffusion wave equation. In general, this problem is ill-posed...  相似文献   
69.
QiuHong Wang  Abdusalam Abdukerim  Wei Chen  Xun Chen  YunHua Chen  XiangYi Cui  YingJie Fan  DeQing Fang  ChangBo Fu  LiSheng Geng  Karl Giboni  Franco Giuliani  LinHui Gu  XuYuan Guo  Ke Han  ChangDa He  Di Huang  Yan Huang  YanLin Huang  Zhou Huang  Peng Ji  XiangDong Ji  YongLin Ju  YiHui Lai  Kun Liang  HuaXuan Liu  JiangLai Liu  WenBo Ma  YuGang Ma  YaJun Mao  Yue Meng  Parinya Namwongsa  KaiXiang Ni  JinHua Ning  XuYang Ning  XiangXiang Ren  ChangSong Shang  Lin Si  AnDi Tan  AnQing Wang  HongWei Wang  Meng Wang  SiGuang Wang  XiuLi Wang  Zhou Wang  MengMeng Wu  ShiYong Wu  JingKai Xia  MengJiao Xiao  PengWei Xie  BinBin Yan  JiJun Yang  Yong Yang  ChunXu Yu  Jumin Yuan  Dan Zhang  HongGuang Zhang  Tao Zhang  Li Zhao  QiBin Zheng  JiFang Zhou  Ning Zhou  XiaoPeng Zhou 《中国科学:物理学 力学 天文学(英文版)》2020,(3):54-63
In dark matter direct detection experiments,neutron is a serious source of background,which can mimic the dark matter-nucleus scattering signals.In this paper,we present an improved evaluation of the neutron background in the PandaX-II dark matter experiment by a novel approach.Instead of fully relying on the Monte Carlo simulation,the overall neutron background is determined from the neutron-induced high energy signals in the data.In addition,the probability of producing a dark-matter-like background per neutron is evaluated with a complete Monte Carlo generator,where the correlated emission of neutron(s)andγ(s)in the(α,n)reactions and spontaneous fissions is taken into consideration.With this method,the neutron backgrounds in the Run 9(26-ton-day)and Run 10(28-ton-day)data sets of PandaX-II are estimated to be(0.66±0.24)and(0.47±0.25)events,respectively.  相似文献   
70.
Yu  Tian-Jun  Zhou  Sha  Yang  Xiao-Dong  Zhang  Wei 《Nonlinear dynamics》2018,91(2):1041-1060
Nonlinear Dynamics - Global dynamics of a flexible asymmetrical rotor resting on vibrating supports is investigated. Hamilton’s principle is used to derive the partial differential governing...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号